Investigation of the Effect of Dual Function Materials (DFM) for the Conversion of Carbon Dioxide (CO2) to Methane (CH4)
Öz
Increasing CO2 emission in the atmosphere due to industrialization causes climate change. For this reason, efforts are being made to reduce, eliminate or convert CO2 emissions. Considering the industrial conditions, the process consists of two steps. The first step is the capture of CO2, a flue gas. The second step is to ensure that the reaction takes place with the help of an external hydrogen feed and its conversion to CH4 to be used as fuel. The roles of bifunctional materials (DFM) in the two mentioned steps are to capture CO2 gas by showing scavenging or absorbing (adsorbent) properties, and then to act as a catalyst in the environment with hydrogen feeding and to ensure an efficient reaction. In industrial conditions, flue gases are expressed by many gas wastes. The capture of CO2 gas among these waste gases with the help of DFM is related to the selectivity of the materials used in DFM. This effect should also manifest itself in the reaction and the conversion of waste gas to fuel by creating side reactions should not be complicated. In this study, the studies carried out on DFM were examined within the framework specified. DFMs turn gas waste into fuel by adsorbing the released CO2 and converting it to synthetic natural gas (methane) at certain temperatures without requiring additional heat. The results of the optimization studies on the metals used as methanation catalysts in DFM and the usage properties of the support materials used with these metals were investigated. Improvement studies and results were compared. It has been reported that an ambient temperature above 320 °C will reduce the efficiency of CO2 capture. It has been reported that the sodium carbonate and aluminum oxide supported (Na2CO3 / Al2O3) material to be used in DFM has an effective selectivity for CO2 capture. At the same time, it was evaluated that the use of platinum group metals in DFM made the methanation reaction more active.
Anahtar Kelimeler
CO2 Capture CO2 Adsorption Dual Function Catalyst DFM (Dual Function Material) Methanation Synthetic Natural Gas
Kaynakça
- Referans1: IPCC, “Climate Change, Synthesis Report Summary Chapter for Policymakers”, IPCC, 2014, p. 31 2014.
- Referans2: I.V Yentekakis, Dong, F. Grand, “Challenges for Catalytic Remediation in Environmental and Energy Applications Toward a Cleaner and Sustainable Future”, Front. Environ. Chem. 1–14, 2020.
- Referans3: F.M. Baena-Moreno, M. Rodríguez-Galán, F. Vega, B. Alonso-Fariñas, L.F. Vilches Arenas, B. Navarrete, “Carbon capture and utilization technologies: A literature review and recent advances”, Energy Sources Part A Recover. Util. Environ. Eff. 1403–1433, 2019.
- Referans4: J. Ashok, S. Pati, P. Hongmanorom, Z. Tianxi, C. Junmei, S. Kawi, “A review of recent catalyst advances in CO2 methanation processes”. Catal. Today, 471–489, 2020.
- Referans5: P.M. Bravo, D.P. Debecker, “Combining CO2 capture and catalytic conversion to methane” Waste Dispos. Sustain. Energy 53–65, 2019.
- Referans6: A.I. Tsiotsias, N.D. Charisiou, I.V. Yentekakis, M.A. Goula, “The Role of Alkali and Alkaline Earth Metals in the CO2 Methanation Reaction and the Combined Capture and Methanation of CO2”, Catalysts, 10, 812, 2020.
- Referans7: M.S. Duyar, M.A. Arellano-Treviño, R.J. Farrauto, “Dual function materials for CO2 capture and conversion using renewable H2”, Appl. Catal. B Environ. 168–169, 370–376, 2015.
- Referans8: H. Sun, Y. Zhang, S. Guan, J. Huang, C. Wu, “Direct and highly selective conversion of captured CO2 into methane through integrated carbon capture and utilization over dual functional materials”. J. CO2 Util. 38, 262–272, 2020.
- Referans9: Z. Zhou, N. Sun, B. Wang, Z. Han, S. Cao, D. Hu, T. Zhu, Q. Shen, W. Wei, “2D-Layered Ni–MgO–Al2O3 Nanosheets for Integrated Capture and Methanation of CO2”. ChemSusChem, 13, 360-368, 2020.
- Referans10: M. Duyar, S. Wang, M.A. Arellano-Treviñob, R.J. Farrauto. “CO2 utilization with a novel dual function material (DFM) for capture and catalytic conversion to synthetic natural gas: An update”, Journal of CO2 Utilization 15, 65—71, (2016).
- Referans11: A. Bermejo-López, B. Pereda-Ayo, J.A. González-Marcos, J.R. González-Velasco. “Ni loading effects on dual function materials for capture and in-situ conversion of CO2 to CH4 using CaO or Na2CO3”, Journal of CO2 Utilization, 34, 576-587, 2019.
- Referans12: M.A. Arellano-Treviño, Z. Hea, M.C. Libby, R.J. Farrauto. “Catalysts and adsorbents for CO2 capture and conversion with dual function materials: Limitations of Ni-containing DFMs for flue gas applications”, Journal of CO2 Utilization, 3, 143-151, 2019.
- Referans13: A. Bermejo-López, B. Pereda-Ayo, J.A. González-Marcos, J.R. González-Velasco. “Modeling the CO2 capture and in situ conversion to CH4 on dual function Ru-Na2CO3/Al2O3 catalyst”, Journal of CO2 Utilization 42, 2020.
- Referans14: A.I. Tsiotsias, N.D. Charisiou, I.V. Yentekakis, M.A. Goula. “Capture and Methanation of CO2 Using Dual Function Materials (DFMs)”, Chemistry Proceeding, 2-35 2020.
- Referans15: L. Proañoa, M.A. Arellano-Treviño, R.J. Farrauto, M. Figueredo, C. Jeong-Potter, M. Cobo. “Mechanistic assessment of dual function materials, composed of Ru-Ni, Na2O/Al2O3 and Pt-Ni, Na2O/Al2O3, for CO2 capture and methanation by insitu DRIFTS”, Applied Surface Science 533, 2020.
- Referans16: B. Shao, Y. Zhang, Z. Sun, J. Lib, Z. Gao, Z. Xie, J. Hua, H. Liu. “CO2 capture and in-situ conversion: recent progresses and perspectives”, Green Chemical Engineering Volume 3, Issue 3, Pages 189-198 September 2022.
- Referans17: J.A. Onrubia-Calvo, A. Bermejo-Lopez, S. Perez-Vazquez, B. Pereda-Ayo, J. Gonzalez-Marcos, J. Gonzalez-Velasco. "Applicability of LaNiO3-derived catalysts as dual function materials for CO2"capture and in-situ conversion to methane", Fuel Volume 320, 15 July 2022.
- Referans18: J. Chen, Y. Xu, P. Liao, H. Wang, H. Zhou. "Recent Progress in Integrated CO2 Capture and Conversion Process Using Dual Function Materials: A State-of-the-Art Review", Carbon Capture Science & Technology Volume 4, September 2022.
- Referans19: C.J. Potter, A. Zangiabadi, R. Farrauto. "Extended aging of Ru-Ni, Na2O/Al2O3 dual function materials (DFM) for combined capture and subsequent catalytic methanation of CO2 from power plant flue gas", Fuel Volume 328, 15 November 2022.
Karbondioksitin (CO2) Metana (CH4) Dönüşümü için Çift İşlevli Malzemelerin (DFM) Etkisinin İncelenmesi
Öz
Endüstrileşme nedeniyle atmosferde artan CO2 emisyonu iklim değişikliğine neden olmaktadır. Bu nedenle CO2 emisyonunu azaltmak, ortadan kaldırmak veya dönüştürmek için çalışmalar yapılmaktadır. Endüstriyel koşullar düşünüldüğünde süreç iki adımdan oluşmaktadır. İlk adım, bir baca gazı olan CO2’in yakalanmasıdır. İkinci adımsa dışarıdan bir hidrojen beslemesi yardımıyla reaksiyonun gerçekleşmesinin sağlanması ve yakıt olarak kullanılacak olan CH4’e dönüşümünün sağlanmasıdır. Çift işlevli malzemelerin (DFM) belirtilen iki adımdaki rolleri yakalayıcı veya soğurucu (adsorban) özelliği göstererek CO2 gazını tutması ve devamında hidrojen beslemesi ile ortamda katalizör etkisi gösterip verimli bir reaksiyon oluşmasını sağlamaktır. Endüstriyel koşullarda baca gazları pek çok gaz atıkları ile ifade edilir. Bu atık gazlar arasından CO2 gazının DFM yardımıyla yakalanması DFM’de kullanılan malzemelerin seçiciliği ile ilgilidir. Bu etki reaksiyonda da kendini göstermeli ve yan reaksiyonlar oluşturarak atık gazın yakıta dönüşmesi karmaşıklaştırılmamalıdır. Bu çalışmada belirtilen çerçevede DFM üzerine gerçekleştirilen çalışmalar incelenmiştir. DFM’ler, salınan CO2’yi adsorbe edip belirli sıcaklıklarda ek ısı gerektirmeden sentetik doğalgaza (metan) dönüştürerek atık gazı yakıta çevirmektedir. DFM’de metanlaştırma (metanasyon) katalizörü olarak kullanılan metallerle ilgili yapılan optimizasyon çalışmalarının sonuçları ve bu metallerle birlikte kullanılan destek malzemelerinin kullanım özellikleri incelenmiştir. Yapılan iyileştirme çalışmaları ve sonuçları karşılaştırılmıştır. Ortam sıcaklığının 320 °C üzerinde olması CO2’in yakalanma verimliliğini düşüreceği raporlanmıştır. DFM’de kullanılacak sodyum karbonat ve alüminyum oksit destekli (Na2CO3 / Al2O3) malzemenin CO2 yakalanması için etkin bir seçicilik özelliği gösterdiği raporlanmıştır. Aynı zamanda platin grubu metallerin DFM’de kullanılmasının metanasyon reaksiyonunu daha aktif kıldığı değerlendirilmiştir.
Anahtar Kelimeler
CO2 Yakalama CO2 Adsorpsiyonu Çift İşlevli Katalizör DFM Metanasyon Sentetik Doğalgaz
Kaynakça
- Referans1: IPCC, “Climate Change, Synthesis Report Summary Chapter for Policymakers”, IPCC, 2014, p. 31 2014.
- Referans2: I.V Yentekakis, Dong, F. Grand, “Challenges for Catalytic Remediation in Environmental and Energy Applications Toward a Cleaner and Sustainable Future”, Front. Environ. Chem. 1–14, 2020.
- Referans3: F.M. Baena-Moreno, M. Rodríguez-Galán, F. Vega, B. Alonso-Fariñas, L.F. Vilches Arenas, B. Navarrete, “Carbon capture and utilization technologies: A literature review and recent advances”, Energy Sources Part A Recover. Util. Environ. Eff. 1403–1433, 2019.
- Referans4: J. Ashok, S. Pati, P. Hongmanorom, Z. Tianxi, C. Junmei, S. Kawi, “A review of recent catalyst advances in CO2 methanation processes”. Catal. Today, 471–489, 2020.
- Referans5: P.M. Bravo, D.P. Debecker, “Combining CO2 capture and catalytic conversion to methane” Waste Dispos. Sustain. Energy 53–65, 2019.
- Referans6: A.I. Tsiotsias, N.D. Charisiou, I.V. Yentekakis, M.A. Goula, “The Role of Alkali and Alkaline Earth Metals in the CO2 Methanation Reaction and the Combined Capture and Methanation of CO2”, Catalysts, 10, 812, 2020.
- Referans7: M.S. Duyar, M.A. Arellano-Treviño, R.J. Farrauto, “Dual function materials for CO2 capture and conversion using renewable H2”, Appl. Catal. B Environ. 168–169, 370–376, 2015.
- Referans8: H. Sun, Y. Zhang, S. Guan, J. Huang, C. Wu, “Direct and highly selective conversion of captured CO2 into methane through integrated carbon capture and utilization over dual functional materials”. J. CO2 Util. 38, 262–272, 2020.
- Referans9: Z. Zhou, N. Sun, B. Wang, Z. Han, S. Cao, D. Hu, T. Zhu, Q. Shen, W. Wei, “2D-Layered Ni–MgO–Al2O3 Nanosheets for Integrated Capture and Methanation of CO2”. ChemSusChem, 13, 360-368, 2020.
- Referans10: M. Duyar, S. Wang, M.A. Arellano-Treviñob, R.J. Farrauto. “CO2 utilization with a novel dual function material (DFM) for capture and catalytic conversion to synthetic natural gas: An update”, Journal of CO2 Utilization 15, 65—71, (2016).
- Referans11: A. Bermejo-López, B. Pereda-Ayo, J.A. González-Marcos, J.R. González-Velasco. “Ni loading effects on dual function materials for capture and in-situ conversion of CO2 to CH4 using CaO or Na2CO3”, Journal of CO2 Utilization, 34, 576-587, 2019.
- Referans12: M.A. Arellano-Treviño, Z. Hea, M.C. Libby, R.J. Farrauto. “Catalysts and adsorbents for CO2 capture and conversion with dual function materials: Limitations of Ni-containing DFMs for flue gas applications”, Journal of CO2 Utilization, 3, 143-151, 2019.
- Referans13: A. Bermejo-López, B. Pereda-Ayo, J.A. González-Marcos, J.R. González-Velasco. “Modeling the CO2 capture and in situ conversion to CH4 on dual function Ru-Na2CO3/Al2O3 catalyst”, Journal of CO2 Utilization 42, 2020.
- Referans14: A.I. Tsiotsias, N.D. Charisiou, I.V. Yentekakis, M.A. Goula. “Capture and Methanation of CO2 Using Dual Function Materials (DFMs)”, Chemistry Proceeding, 2-35 2020.
- Referans15: L. Proañoa, M.A. Arellano-Treviño, R.J. Farrauto, M. Figueredo, C. Jeong-Potter, M. Cobo. “Mechanistic assessment of dual function materials, composed of Ru-Ni, Na2O/Al2O3 and Pt-Ni, Na2O/Al2O3, for CO2 capture and methanation by insitu DRIFTS”, Applied Surface Science 533, 2020.
- Referans16: B. Shao, Y. Zhang, Z. Sun, J. Lib, Z. Gao, Z. Xie, J. Hua, H. Liu. “CO2 capture and in-situ conversion: recent progresses and perspectives”, Green Chemical Engineering Volume 3, Issue 3, Pages 189-198 September 2022.
- Referans17: J.A. Onrubia-Calvo, A. Bermejo-Lopez, S. Perez-Vazquez, B. Pereda-Ayo, J. Gonzalez-Marcos, J. Gonzalez-Velasco. "Applicability of LaNiO3-derived catalysts as dual function materials for CO2"capture and in-situ conversion to methane", Fuel Volume 320, 15 July 2022.
- Referans18: J. Chen, Y. Xu, P. Liao, H. Wang, H. Zhou. "Recent Progress in Integrated CO2 Capture and Conversion Process Using Dual Function Materials: A State-of-the-Art Review", Carbon Capture Science & Technology Volume 4, September 2022.
- Referans19: C.J. Potter, A. Zangiabadi, R. Farrauto. "Extended aging of Ru-Ni, Na2O/Al2O3 dual function materials (DFM) for combined capture and subsequent catalytic methanation of CO2 from power plant flue gas", Fuel Volume 328, 15 November 2022.
Ayrıntılar
| Birincil Dil | Türkçe |
|---|---|
| Konular | Kimya Mühendisliği |
| Bölüm | Makaleler |
| Yazarlar | |
| Erken Görünüm Tarihi | 11 Aralık 2023 |
| Yayımlanma Tarihi | 31 Aralık 2023 |
| Yayımlandığı Sayı | Yıl 2023 Cilt: 11 Sayı: 1 |
