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Yüksek Fırın Cürufu, Kalsine Kaolin ve Diatomit İkameli Çimentoların Yapısal Özeliklerinin Eğilme Dayanımına Etkisi

Yıl 2024, Cilt: 12 Sayı: 1, 400 - 418, 26.01.2024

Ayperi Tanık Yılmaz Koçak

https://doi.org/10.29130/dubited.1257545

Öz

Çimento ve beton teknolojisinde tercih edilen yüksek fırın cürufu (YFC), kalsine kaolin ve diatomit gibi mineral katkıların kullanımı her geçen gün artmaktadır. Bu malzemelerin yapısal özelliklerine bağlı olarak, betonun dayanım ve dayanıklılığında olumlu değişikliklerin meydana geldiği belirtilmektedir. Bu bağlamda mineral katkıların fiziksel ve kimyasal özelliklerinin yanı sıra, mineralojik, moleküler, termal ve mikro yapı gibi özelliklerinin belirlenmesinin de faydalı olabileceği düşünülmektedir. Bu amaçla ilk aşamada Portland çimento (PÇ), YFC, kalsine kaolin ve diatomitin fiziksel, kimyasal, mineralojik, moleküler, termal ve mikro yapı gibi yapısal özellikleri belirlenmiştir. İkinci aşamada YFC, kalsine kaolin ve diatomit, PÇ yerine ağırlıkça %10 oranlarında ikame edilerek, biri referans olmak üzere toplam 4 tip çimento elde edilmiştir. Son aşamada ise bu çimentolarla üretilen harç numunelerinin 2, 7, 28 ve 90. günlerde eğilme dayanım değerleri belirlenmiştir. Sonuç olarak harç numunelerinin eğilme dayanım değerlerinin, hidratasyon sürelerine ve mineral katkıların yapısal özelliklerine bağlı olarak farklılık gösterdiği belirtilebilir. Ayrıca YFC ikameli çimento harcının 90. günde neredeyse referans çimentonun eğilme dayanım değerine sahip olduğu ve diğer puzolanik malzemelere göre eğilme dayanımı açısından nispeten daha olumlu katkı sağladığı ifade edilebilir.

Anahtar Kelimeler

Portland çimento yüksek fırın cürufu kalsine kaolin diatomit yapısal özellikler eğilme dayanımı

Teşekkür

Yazarlar, standart çimento deneylerinin yapılmasında desteklerini esirgemeyen Eskişehir Çimento Fabrikası laboratuvar çalışanları ve idarecilerine içtenlikle teşekkür ederler.

Kaynakça

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Effect of Structural Properties of Blast Furnace Slag, Calcined Kaolin and Diatomite Substituted Cements on Flexural Strength

Yıl 2024, Cilt: 12 Sayı: 1, 400 - 418, 26.01.2024

Ayperi Tanık Yılmaz Koçak

https://doi.org/10.29130/dubited.1257545

Öz

The use of mineral additives such as blast furnace slag (BFS), calcined kaolin and diatomite, which are preferred in cement and concrete technology, is increasing day by day. It is stated that positive changes occur in the strength and durability of concrete depending on the structural properties of these materials. In this context, besides the physical and chemical properties of mineral additives, it is thought that it may be useful to determine the properties such as mineralogical, molecular, thermal and microstructure. For this purpose, in the first stage, structural properties such as physical, chemical, mineralogical, molecular, thermal and microstructure of Portland cement (PC), BFS, calcined kaolin and diatomite were determined. In the second stage, a total of 4 types of cement, one of which is a reference, were obtained by substituting BFS, calcined kaolin and diatomite at 10% by weight instead of PC. At the last stage, the flexural strength values of the mortar samples produced with these cements were determined at the 2-day, 7-day, 28-day and 90-day. As a result, it can be stated that the flexural strength values of the mortar samples differ depending on the hydration times and the structural properties of the mineral admixtures. Furthermore, it can be stated that the cement mortar with BFS additives has values close to the flexural strength of the reference cement at 90-day, and provides a relatively more positive contribution in terms of flexural strength compared to other pozzolanic materials.

Anahtar Kelimeler

Portland cemen blast furnace slag calcined kaolin diatomite structural features flexural strength

Kaynakça

  • [1] K. Fang, D. Wang, J. Zhao and M. Zhang “Utilization of ladle furnace slag as cement partial replacement: Influences on the hydration and hardening properties of cement,” Construction and Building Materials, vol. 299, no. 124265, 2021.
  • [2] B. Chen, L. Pang, Z. Zhou, Q. Chang, and P. Fu, “Study on the hydration properties of a ternary cementitious material system containing activated gold tailings and granulated blast furnace slag,” Journal of Building Engineering, vol. 63, no. 105574, 2023.
  • [3] E. Gödek, K. T. Felekoğlu, M. Keskinateş, and B. Felekoğlu, “Development of flaw tolerant fiber reinforced cementitious composites with calcined kaolin,” Applied Clay Science, vol. 146, pp.423-431, 2017.
  • [4] M. Karatas, A. Benli, and F. Arslan, “The effects of kaolin and calcined kaolin on the durability and mechanical properties of self-compacting mortars subjected to high temperatures,” Construction and Building Materials, vol. 265, no. 120300, 2020.
  • [5] O. Alselwi, B. X. Li, S. Liu Yue, and W. Zhi Wen, “Efficacy of sodium alginate, xanthan gum, and diatomite admixtures in improving the strength and shrinkage behaviour of EPS lightweight concrete,” European Journal of Environmental and Civil Engineering, pp.1-14, 2022. (Early Access)
  • [6] Z. Lv, A. Jiang, and J. Jin, “Influence of ultrafine diatomite on cracking behavior of concrete: An acoustic emission analysis,” Construction and Building Materials, vol. 308, no. 124993, 2021.
  • [7] J. Liu, Q. Yu, Z. Zuo, F. Yang, W. Duan, and Q. Qin, “Blast furnace slag obtained from dry granulation method as a component in slag cement,” Construction and Building Materials, vol. 131, pp.381-387, 2017.
  • [8] M. Tokyay ve K. Erdoğdu, “Cüruflar ve cüruflu çimentolar,” TÇMB/AR-GE/Y97.2, Ankara, 1997.
  • [9] H. Yalçın ve M. Gürü, Çimento ve Beton, Ankara, Türkiye: Palme Yayıncılık, 2006, böl. 3, ss. 38.
  • [10] F. Arslan, “Kaolin kullanımının kendiliğinden yerleşen harçların dayanım ve dayanıklılık özelliklerine etkisi,” Yüksek Lisans Tezi, İnşaat Mühendisliği, Fırat Üniversitesi, Elazığ, Türkiye, 2019.
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  • [12] Z. Yılmaz, “Hidrotermal yöntemlerle kaolin’in dekompozisyonu,” Yüksek Lisans Tezi, Kimya, Balıkesir Üniversitesi, Balıkesir Türkiye, 2004.
  • [13] G. Kakali, T. H. Perraki, S. Tsivilis, and E. Badogiannis, “Thermal treatment of kaolin: the effect of mineralogy on the pozzolanic activity,” Applied clay science, vol. 20, no. 1-2, pp.73-80, 2001.
  • [14] A. Shvarzman, K. Kovler, G. S. Grader, and G. E. Shter, “The effect of dehydroxylation/amorphization degree on pozzolanic activity of kaolinite,” Cement and concrete research, vol. 33, no. 3, pp.405-416, 2003.
  • [15] E. Badogiannis, G. Kakali, and S. Tsivilis, “Metakaolin as supplementary cementitious material: optimization of kaolin to metakaolin conversion,” Journal of thermal analysis and calorimetry, vol. 81, no. 2, pp.457-462, 2005.
  • [16] Ç. Salam, “Fiziksel ve kimyasal işlemlerin kaolin’in yapısına etkileri” Yüksek lisans tezi, Kimya Ana Bilim Dalı, Fen Bilimleri Enstitüsü, Balıkesir Üniversitesi, Balıkesir, 2004.
  • [17] Z. Ahmadi, J. Esmaeili, J. Kasaei, and R. Hajialioghli, “Properties of sustainable cement mortars containing high volume of raw diatomite,” Sustainable Materials and Technologies, vol. 16, pp.47-53, 2018.
  • [18] H.Y. Aruntaş, “Diatomitlerin çimentolu sistemlerde puzolanik malzeme olarak kullanılabilirliği,” Doktora Tezi, Mimarlık, Gazi Üniversitesi, Ankara, Türkiye, 1996. [19] A. Uygun, Diatomit Jeolojisi, ve yararlanma olanakları. Bilimsel Madencilik Dergisi, c. 15, s. 5, ss. 31-38, 1976.
  • [20] Çalışkan M. “Doğal Diatomit (Çaldıran-Van) Üzerine Basic Blue Ve Neutral Red Boyar Maddelerinin Adsorpsiyon ve Denge Çalışması,” Yüksek Lisans Tezi, Kimya, Ordu Üniversitesi, Ordu, Türkiye, 2018.
  • [21] S. Benayache, S. Alleg, A. Mebrek, and J. J. Suñol, “Thermal and microstructural properties of paraffin/diatomite composite,” Vacuum, vol. 157, pp.136-144, 2018.
  • [22] E. Worrell, N. Martin and L. Price, “Potentials for energy efficiency improvement in the US cement industry,” Energy, vol. 25, no. 12, pp.1189-1214, 2000.
  • [23] A. Hasanbeigi, L. Price and E. Lin, “Emerging energy-efficiency and CO2 emission-reduction technologies for cement and concrete production: A technical review,” Renewable and Sustainable Energy Reviews, vol. 16, no. 8, pp. 6220-6238, 2012.
  • [24] S. R. Salla, R. B. Uppara, A. K. Kannazia, B. Kondraivendhan, and C. D. Modhera, “An experimental and environmental impact assessment of slag-based mineral admixture for sustainable development,” Innovative Infrastructure Solutions, vol. 8, no. 29, 2023.
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Toplam 67 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Konular Mühendislik
Bölüm Makaleler
Yazarlar

Ayperi Tanık 0000-0002-5172-9331

Yılmaz Koçak 0000-0002-5281-5450

Yayımlanma Tarihi 26 Ocak 2024
Yayımlandığı Sayı Yıl 2024 Cilt: 12 Sayı: 1

Kaynak Göster

APA Tanık, A., & Koçak, Y. (2024). Yüksek Fırın Cürufu, Kalsine Kaolin ve Diatomit İkameli Çimentoların Yapısal Özeliklerinin Eğilme Dayanımına Etkisi. Düzce Üniversitesi Bilim Ve Teknoloji Dergisi, 12(1), 400-418. https://doi.org/10.29130/dubited.1257545
AMA Tanık A, Koçak Y. Yüksek Fırın Cürufu, Kalsine Kaolin ve Diatomit İkameli Çimentoların Yapısal Özeliklerinin Eğilme Dayanımına Etkisi. DÜBİTED. Ocak 2024;12(1):400-418. doi:10.29130/dubited.1257545
Chicago Tanık, Ayperi, ve Yılmaz Koçak. “Yüksek Fırın Cürufu, Kalsine Kaolin Ve Diatomit İkameli Çimentoların Yapısal Özeliklerinin Eğilme Dayanımına Etkisi”. Düzce Üniversitesi Bilim Ve Teknoloji Dergisi 12, sy. 1 (Ocak 2024): 400-418. https://doi.org/10.29130/dubited.1257545.
EndNote Tanık A, Koçak Y (01 Ocak 2024) Yüksek Fırın Cürufu, Kalsine Kaolin ve Diatomit İkameli Çimentoların Yapısal Özeliklerinin Eğilme Dayanımına Etkisi. Düzce Üniversitesi Bilim ve Teknoloji Dergisi 12 1 400–418.
IEEE A. Tanık ve Y. Koçak, “Yüksek Fırın Cürufu, Kalsine Kaolin ve Diatomit İkameli Çimentoların Yapısal Özeliklerinin Eğilme Dayanımına Etkisi”, DÜBİTED, c. 12, sy. 1, ss. 400–418, 2024, doi: 10.29130/dubited.1257545.
ISNAD Tanık, Ayperi - Koçak, Yılmaz. “Yüksek Fırın Cürufu, Kalsine Kaolin Ve Diatomit İkameli Çimentoların Yapısal Özeliklerinin Eğilme Dayanımına Etkisi”. Düzce Üniversitesi Bilim ve Teknoloji Dergisi 12/1 (Ocak 2024), 400-418. https://doi.org/10.29130/dubited.1257545.
JAMA Tanık A, Koçak Y. Yüksek Fırın Cürufu, Kalsine Kaolin ve Diatomit İkameli Çimentoların Yapısal Özeliklerinin Eğilme Dayanımına Etkisi. DÜBİTED. 2024;12:400–418.
MLA Tanık, Ayperi ve Yılmaz Koçak. “Yüksek Fırın Cürufu, Kalsine Kaolin Ve Diatomit İkameli Çimentoların Yapısal Özeliklerinin Eğilme Dayanımına Etkisi”. Düzce Üniversitesi Bilim Ve Teknoloji Dergisi, c. 12, sy. 1, 2024, ss. 400-18, doi:10.29130/dubited.1257545.
Vancouver Tanık A, Koçak Y. Yüksek Fırın Cürufu, Kalsine Kaolin ve Diatomit İkameli Çimentoların Yapısal Özeliklerinin Eğilme Dayanımına Etkisi. DÜBİTED. 2024;12(1):400-18.
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